Search results for "Tetrabutylammonium bromide"

showing 3 items of 3 documents

A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

2015

Primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones by using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of the bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% TEMPO.

Allylic rearrangementalcoholoxidationOrganic ChemistryketoneEthyl acetatecatalysiSettore CHIM/06 - Chimica OrganicaMedicinal chemistryaldehydeCatalysischemistry.chemical_compoundchemistryTetrabutylammonium bromideAlcohol oxidationBenzeneBromide ions
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CCDC 1040203: Experimental Crystal Structure Determination

2016

Related Article: Markus Albrecht, Yi Hai, Okan Köksal, Gerhard Raabe, Fangfang Pan, Arto Valkonen and Kari Rissanen|2016|Chem.-Eur.J.|22|6596|doi:10.1002/chem.201600249

Space GroupCrystallographytetrabutylammonium bromide bis(35-bis(trifluoromethyl)benzamide)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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ChemInform Abstract: A Simple Procedure for the Oxidation of Alcohols Using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl…

2015

Primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones by using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of the bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% TEMPO.

chemistry.chemical_compoundAllylic rearrangementchemistryAlcohol oxidationTetrabutylammonium bromideEthyl acetateOrganic chemistryGeneral MedicineBenzeneBromide ionsCatalysisChemInform
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